The reactivities of amines towards the N-phosphorylpyridinium ions are weakly dependent on the basicities of the amines, but other features of amine structure are important. It is argued that the transition states for displacement reactions at the phosphorus atom of phosphate derivatives have the pentaoxyphosphorane structure.
G. W. Jameson and J. M. Lawlor, J. Chem. Soc. B, 1970, 53 DOI: 10.1039/J29700000053
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