Issue 0, 1970
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Disproportionation of trifluoromethyl and isopropyl radicals

P. Cadman,   Y. Inel  and  A. F. Trotman-Dickenson  

Abstract

Mixtures of hexafluoroacetone–di-isopropyl ketone were photolysed between 32 and 115°. The disproportionation–combination ratio of trifluoromethyl and isopropyl radicals was measured. Allowance was made for the consumption of the disproportionation product, propene, by trifluoromethyl radical addition.

The disproportionation–combination ratio was found to be 2·2 ± 0·2 and independent of temperature. This value is considerably greater than that found in similar nonfluorinated radicals.

A re-examination of the disproportionation–combination ratio of isopropyl radicals gave a value of 0·61 ± 0·1.

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Article information

DOI
https://doi.org/10.1039/J19700001207
Article type
Paper

J. Chem. Soc. A, 1970, 1207-1209

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Disproportionation of trifluoromethyl and isopropyl radicals

P. Cadman, Y. Inel and A. F. Trotman-Dickenson, J. Chem. Soc. A, 1970, 1207 DOI: 10.1039/J19700001207

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