There is no reaction between IrCl(CO)(PPh3)2 and AuCl(PPh3) in benzene solution under oxygen-free nitrogen. The physical properties and reactions ascribed to the supposed iridium–gold compound, Cl2(CO)(PPh3)2Ir·Au(PPh3), are instead to be attributed to the oxygen complex, Ir(O2)Cl(CO)(PPh3)2.
C. A. Reed and W. R. Roper, J. Chem. Soc. A, 1970, 506 DOI: 10.1039/J19700000506
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