The pyrolysis of nopinol gives the hydroxyolefin(6) and the aldehyde (5)via abnormal C-5–C-6, C-1–C-7 cleavage of the pinane cyclobutane ring, the mode of formation of the aldehyde being established by deuterium labelling experiments.
J. M. Coxon, R. P. Garland and M. P. Hartshorn, J. Chem. Soc. D, 1970, 1709b DOI: 10.1039/C2970001709B
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