Bis-(π-cyclopentadienyldicarbonyliron)(I) is oxidised by an excess of anhydrous ferric perchlorate in acetone, yielding solutions of [(π-C5H5)Fe(CO)2OCMe2]+(IIa), which, on treatment with various ligands, gives complexes of the types [(π-C5H5)Fe(CO)2L]+(II) and (π-C5H5)Fe(CO)2X (III).
E. C. Johnson, T. J. Meyer and N. Winterton, J. Chem. Soc. D, 1970, 934b DOI: 10.1039/C2970000934B
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