A single-crystal X-ray study of [SPMe2NPMe2S]2Fe shows its FeII centre to be tetrahedrally co-ordinated by four sulphur atoms: the molecule is suggested as a structural model for the iron–sulphur core of rubredoxin.
M. R. Churchill and J. Wormald, J. Chem. Soc. D, 1970, 703b DOI: 10.1039/C2970000703B
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