Analysis of the hyperfine coupling constants for these radicals show that the unpaired electrons are in σ-bonds comprising largely the outer s-orbitals of the atoms: these atoms have equal spin-densities in Cd23+ and AgCd2+, but mercury is favoured in AgHg2+.
R. S. Eachus, I. Marov and M. C. R. Symons, J. Chem. Soc. D, 1970, 633a DOI: 10.1039/C2970000633A
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