The rate constants for the reaction of Fe2+ and Mn2+ with @#x0323;Br2– and the rapid formation of FeBr2+ by this reaction provide direct evidence for an inner-sphere mechanism for these fast oxidation reactions.
A. T. Thornton and G. S. Laurence, J. Chem. Soc. D, 1970, 443b DOI: 10.1039/C2970000443B
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