Secondary kinetic deuterium isotope effects in vinyl cations
Abstract
The β-deuterium isotope effect in the solvolysis of β-styryl trifluoromethanesulphonate (1), kH/kD= 1·42, is much larger than in normal carbonium ions.
The β-deuterium isotope effect in the solvolysis of β-styryl trifluoromethanesulphonate (1), kH/kD= 1·42, is much larger than in normal carbonium ions.
R. J. Hargrove, T. E. Dueber and P. J. Stang, J. Chem. Soc. D, 1970, 1614 DOI: 10.1039/C29700001614
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