The high-temperature hydration of norbornadiene at 250° in 10% HOAc–H2O initially yields norbornenols, nortricyclanol, and norbornanediols which are gradually converted into cyclopent-2- and -3-eneacetaldehydes, cyclohex-3-enecarboxaldehyde, and norcamphor.
N. H. Werstiuk and T. Kadai, J. Chem. Soc. D, 1970, 1613 DOI: 10.1039/C29700001613
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