O,S-Ethylene O-methyl phosphorothioate is found to undergo nucleophilic attack by hydroxide ion with P–S cleavage which contrasts with the behaviour of related cyclic O,S-esters previously reported.
D. C. Gay and N. K. Hamer, J. Chem. Soc. D, 1970, 1564 DOI: 10.1039/C29700001564
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