Anchimeric assistance by the neighbouring oxime function in acid hydrolysis of alkyl α-hydroxyimino-p-nitrobenzyl alkylphosphonates (III), besides increasing the rate of de-esterification by ca. 107 compared with simple phosphonates (I), leads to P–O fission, normally associated with alkaline hydrolysis of the latter.
J. I. G. Cadogan and D. T. Eastlick, J. Chem. Soc. D, 1970, 1546 DOI: 10.1039/C29700001546
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