In the presence of catalytic quantities of mineral acid the oxymercuration of olefins is a thermodynamically controlled process, equilibration occurring by reversible oxymercuration–deoxymercuration, and at least for the system studied, mercurinium ions are not kinetically important intermediates in oxymercuration.
S. Bentham, P. Chamberlain and G. H. Whitham, J. Chem. Soc. D, 1970, 1528 DOI: 10.1039/C29700001528
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...