Issue 22, 1970
From the journal:

Journal of the Chemical Society D: Chemical Communications

Tristrifluoromethylbis(trimethylsiloxy)phosphorane, (CF3)3P[OSi(CH3)3]2, and bistrifluoromethyltrimethylsiloxyphosphine oxide, (CF3)2P(O)OSi(CH3)3

R. G. Cavell  and  R. D. Leary  

Abstract

Direct combination of (CF3)3PO with hexamethyldisiloxane yields the new phosphorane (CF3)3P(OSiMe3)2 which thermally decomposes to (CF3)2P(O)OSiMe3; the latter new compound can also be obtained by reaction of (CF3)2P(O)Cl with hexamethyldisiloxane.

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Article information

DOI
https://doi.org/10.1039/C29700001520
Article type
Paper

J. Chem. Soc. D, 1970, 1520-1521

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Tristrifluoromethylbis(trimethylsiloxy)phosphorane, (CF3)3P[OSi(CH3)3]2, and bistrifluoromethyltrimethylsiloxyphosphine oxide, (CF3)2P(O)OSi(CH3)3

R. G. Cavell and R. D. Leary, J. Chem. Soc. D, 1970, 1520 DOI: 10.1039/C29700001520

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