The crystal structure of the dimer of bis-(o-xylene)silver perchlorate has been determined by single-crystal methods: the dimer is made up of oxygen-bridged silver(I) with the fourfold co-ordination of the metal completed by interaction with the π-electrons of two aromatic entities.
I. F. Taylor and E. L. Amma, J. Chem. Soc. D, 1970, 1442 DOI: 10.1039/C29700001442
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