A series of cationic PdII alkyl sulphoxide complexes is found to exhibit regular structural changes from cis-S- and O-bonded to trans-S- and O-bonded to entirely O-bonded forms as the steric requirements of the alkyl group increase from methyl to isopentyl.
J. H. Price, R. F. Schramm and B. B. Wayland, J. Chem. Soc. D, 1970, 1377 DOI: 10.1039/C29700001377
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