The synthesis of fluorocarbon–gold complexes from Ph3PAuMe is described, including the preparation of binuclear species [Ph3PAu]2(AB)[AB =(CF3)2CO, (CF3)2CNH, and (CF3)2C2]: whereas the gold–carbon bond in Ph3PAuC2F4Me is cleaved by bromine, a gold(III) complex Ph3PAu(C2B10H10Ph)(Br)2 is obtained from Ph3PAu(C2B10H10Ph), an example of a very stable new class of organogold(I) compound.
C. M. Mitchell and F. G. A. Stone, J. Chem. Soc. D, 1970, 1263 DOI: 10.1039/C29700001263
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...