d-Orbital participation in the bonding in molecules containing phosphorus, sulphur, and chlorine is discussed with the aid of ab initio SCF–MO calculations on ClO2–, ClO3–, ClO4–, PF3O, SO2F2, and ClO3F.
I. H. Hillier and V. R. Saunders, J. Chem. Soc. D, 1970, 1183 DOI: 10.1039/C29700001183
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