A deshielding effect which has been observed for the anomeric proton of a number of thionucleosides was ascribed to the anistropy effect of a thione group and has provided a new method for the structural assignment of certain isomeric thionucleosides.
R. A. Long and L. B. Townsend, J. Chem. Soc. D, 1970, 1087 DOI: 10.1039/C29700001087
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