It has been claimed that nucleophilic substitution in the mechanistic border-line region occurs by a single mechanism via an intermediate ion-pair, but it is now shown that the relevant results are equally consistent with concurrent unimolecular and bimolecular processes.
B. J. Gregory, G. Kohnstam, M. Paddon-Row and A. Queen, J. Chem. Soc. D, 1970, 1032 DOI: 10.1039/C29700001032
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