The A1 and F2 Zn–N stretching vibrations of the Raman spectrum of solid [Zn(NH3)4]I2 have been assigned by using the metal isotope technique: the A1 mode shows almost no dependence on the isotopic substitution of the central metal atom, whereas the F2 mode is metal isotope-sensitive.
J. Takemoto and K. Nakamoto, J. Chem. Soc. D, 1970, 1017 DOI: 10.1039/C29700001017
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