The complex trans-[ReCl(N2)(PMe2Ph)4] reacts with a great variety of electron-acceptor molecules to form polynuclear dinitrogen complexes, apparently by addition of the acceptor atom to the terminal nitrogen atom of the dinitrogen ligand.
J. Chatt, J. R. Dilworth, G. J. Leigh and R. L. Richards, J. Chem. Soc. D, 1970, 955 DOI: 10.1039/C29700000955
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