In the crystal of the complex [{Ph2P(O)·CH2·P(O)Ph2}3Na]Br,3H2O the cation consists of three molecules of the bis(phosphine oxide) chelating a sodium ion by a trigonal prismatic arrangement of six oxygens.
W. Hewertson, B. T. Kilbourn and R. H. B. Mais, J. Chem. Soc. D, 1970, 952 DOI: 10.1039/C29700000952
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