Issue 15, 1970

Stereoselectivity in the addition of chlorofluorocarbene to 10-methyl-Δ8-2-octalone 2-ethylene acetal

Abstract

Chlorofluorocarbene adds to the title olefin (I) with very marked β-endo-F stereoselectivity to give a mixture of the cyclopropane (II)(80–90%) and an unidentified product (10–20%).

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 927-928

Stereoselectivity in the addition of chlorofluorocarbene to 10-methyl-Δ8-2-octalone 2-ethylene acetal

R. A. Moss, R. W. Kleinman and K. L. Williamson, J. Chem. Soc. D, 1970, 927 DOI: 10.1039/C29700000927

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