In the oxymercuration–demercuration of long-chain unsaturated esters the presence of a substituent (OH, OMe, OAc) affects the proportion of the two isomeric products and, in some cases, furnishes novel products through interaction of the substituent with the intermediate mercury compound.
F. D. Gunstone and R. P. Inglis, J. Chem. Soc. D, 1970, 877 DOI: 10.1039/C29700000877
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