Issue 13, 1970

Use of the fluorescence of lanthanide complexes to study the kinetics of a ligand-transfer reaction

Abstract

The kinetics of the transfer of a 2,2′6′,2″-terpyridyl (terpy) molecule from [Eu terpy3]3+ to Tb3+ in nitromethane solution have been determined by a study of the fluorescence of the europium complex; the reaction is first order in [Eu terpy3]3+, independent of the Tb3+ concentration, and has t½= 6·1 min. at 2·8°.

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 836-836

Use of the fluorescence of lanthanide complexes to study the kinetics of a ligand-transfer reaction

G. H. Frost and F. A. Hart, J. Chem. Soc. D, 1970, 836 DOI: 10.1039/C29700000836

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