A transannular hydride shift in the bicyclo[3,3,2]decane system
Abstract
Buffered acetolysis of exo-3-2,2,3,4,4-pentadeuteriobicyclo[3,3,2]decyl toluene-p-sulphonate is accompanied by 48% transannular hydride shift probably involving a specific C(7) to C(3) hydrogen migration.