A vapour-phase i.r. spectroscopic study of cyanamide, NH2CN, and its deuteriated equivalents gives values for the small moment of inertia and higher vibrational transitions associated with the inversion mode; from these data estimates are made of 43 ± 1·5° for the out-of-plane angle and 467 ± 30 cm–1 for the barrier to inversion.
T. R. Jones and N. Sheppard, J. Chem. Soc. D, 1970, 715 DOI: 10.1039/C29700000715
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