Issue 12, 1970

Intramolecular addition of benzyl-lithium derivatives to norbornene rings

Abstract

Although α-aryl substituents stabilize organo-lithium reagents in tetrahydrofuran, such derivatives can attack a norbornene double-bond intramolecularly to produce a more reactive, tricyclic s-alkyl-lithium that appears to abstract a proton preferentially from the solvent.

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 714-715

Intramolecular addition of benzyl-lithium derivatives to norbornene rings

P. T. Lansbury and F. J. Caridi, J. Chem. Soc. D, 1970, 714 DOI: 10.1039/C29700000714

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