The temperature dependence of the n.m.r. spectra of NN′-diaryl-NN′-dialkylhydrazines is consistent with a substantial barrier to rotation about the N–N bond, but similar temperature dependence of the n.m.r. spectra of NN-dialkylhydroxylamines may be associated with a high barrier to nitrogen inversion.
J. R. Fletcher and I. O. Sutherland, J. Chem. Soc. D, 1970, 687 DOI: 10.1039/C29700000687
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