Absolute rate constants for the SH2 process RO·+ BBu3→ ROBBu2+ Bu· have been obtained by two competition techniques involving the analysis of products by g.l.c., or of the radical intermediates by e.s.r.
A. G. Davies, D. Griller, B. P. Roberts and R. Tudor, J. Chem. Soc. D, 1970, 640 DOI: 10.1039/C29700000640
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