The crystal structure of the heterocyclic molecule 1,3-dimethyl-2(3H)-imidazolethione and its 1H n.m.r. spectrum have been interpreted as showing partial double-bond character in the N–C–N system, but no aromaticity.
G. B. Ansell, D. M. Forkey and D. W. Moore, J. Chem. Soc. D, 1970, 56b DOI: 10.1039/C2970000056B
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