The n.m.r. spectrum of the compound (π-C4H7)PdCl(PPhMeMe′) reveals two simultaneous interchange reactions—interchange of the two nonequivalent methyl groups and interchange of allyl protons (3) and (4)—thus proving that the intermediate of the (3)–(4) interchange reaction contains a σ-bonded methyllyl group.
P. W. N. M. van Leeuwen and A. P. Praat, J. Chem. Soc. D, 1970, 365 DOI: 10.1039/C29700000365
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