Manganese(III) acetylacetonate, in the presence of a suitable electron donor such as dimethyl sulphoxide, is an active, selective, initiator of free-radical polymerization at 25°, the order for the monomers studied being acrylonitrile > methyl methacrylate > styrene: suggested mechanisms for selective and nonselective components of the reaction involve ligand displacement.
C. H. Bamford and A. N. Ferrar, J. Chem. Soc. D, 1970, 315 DOI: 10.1039/C29700000315
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