Brominations of some 2,6-dialkylphenyl acetates in nitromethane give the 4-bromo-2,6-dialkylphenyl acetates together with the corresponding 4-bromo-2,6-dialkyl phenols, whereas 3-substitution predominates for the corresponding brominations and chlorinations in acetic acid.
P. B. D. de la Mare and B. N. B. Hannan, J. Chem. Soc. D, 1970, 156 DOI: 10.1039/C29700000156
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