Both the compounds mentioned in the title contain the [Nb(O2)3(C12H8N2)]– ion in which the niobium atom is eight-co-ordinate; the water and H2O2 molecules form hydrogen bonds with the co-ordinated oxygens.
G. Mathern, R. Weiss and R. Rohmer, J. Chem. Soc. D, 1970, 153 DOI: 10.1039/C29700000153
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