A stabilizing 2-4′-endo-interaction in the transition state is supported by the observed faster rate of reaction of hexachlorocyclopentadiene with αβ-unsaturated dieneophiles capable of assuming a cisoid conformation.
C. G. Cárdenas, J. Chem. Soc. D, 1970, 134 DOI: 10.1039/C29700000134
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