(±)-Tylophorine was synthesised by a route involving as a key step the highly selective reduction of an amide to the corresponding amine in the presence of an ester function with triethyloxonium fluoroborate followed by sodium borohydride.
R. B. Herbert and C. J. Moody, J. Chem. Soc. D, 1970, 121 DOI: 10.1039/C29700000121
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