It is shown that the adducts SOF4·AsF5 and SOF4·SbF5 have the ionic structure SOF3+MF6– in the solid state and in solution in hydrogen fluoride: the vibrational spectrum of the SOF3+ ion is assigned and the bonding in the ion is discussed.
M. Brownstein, P. A. W. Dean and R. J. Gillespie, J. Chem. Soc. D, 1970, 9 DOI: 10.1039/C29700000009
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