The effect of a non-spherical solvent cavity on the solution/gas intensity ratio has been computed. The dimensions of the cavity have a considerably geater effect on As/Ag ratios than is generally appreciated. Such an effect can account for As/Ag ratios which are less than unity.
J. G. David and H. E. Hallam, Trans. Faraday Soc., 1969, 65, 2843 DOI: 10.1039/TF9696502843
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