From force constants derived from experimentally obtained vibrational frequencies, bond orders for the NSi and NGe bonds of HNSi and HNGe, assumed to be linear triatomic molecules, have been estimated to be 2.7 and 2.3. Inferences regarding the nature of the bonding in these unusual molecules are briefly discussed.
J. F. Ogilvie and M. J. Newlands, Trans. Faraday Soc., 1969, 65, 2602 DOI: 10.1039/TF9696502602
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