Volume 65, 1969

Use of charge transfer spectrum to study autoxidation. Part 3.—The thermally-initiated autoxidation of tetralin

Abstract

The thermally-initiated autoxidation of tetralin has been studied by observing the decay of the oxygen-tetralin charge transfer spectrum. The relative rate constants and activation energies have been determined for the propagation and self-termination reactions and for termination with the retarder 2,6-di-t-butyl-4-methylphenol. The possible formation of an oxygen-tetralin complex and the molecular reaction between oxygen and tetralin are considered. The applicability of the charge transfer spectrum method is surveyed.

Article information

Article type
Paper

Trans. Faraday Soc., 1969,65, 2144-2149

Use of charge transfer spectrum to study autoxidation. Part 3.—The thermally-initiated autoxidation of tetralin

J. Betts and J. C. Robb, Trans. Faraday Soc., 1969, 65, 2144 DOI: 10.1039/TF9696502144

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