The equilibria (MH3)2E + H2E⇌2MH3EH (E = S, Se, Te; M = Si, Ge) have been studied by 1H nuclear magnetic resonance spectroscopy. The spectra of the new compounds MH3EH(E = Se, Te; M = Si: E = S, Se, Te; M = Ge) are reported, including satellites due to 29Si, 77Se and 125Te at natural abundance. The 125TeH coupling constant in H2Te is also reported for the first time.
C. Glidewell, D. W. H. Rankin and G. M. Sheldrick, Trans. Faraday Soc., 1969, 65, 1409 DOI: 10.1039/TF9696501409
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