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The magnetic circular dichroism (MCD) spectra observed for the n–π* transition of fifty-three aldehydes and ketones are reported. The results show that, with appropriate instrumentation, MCD spectra can be obtained for all carbonyl compounds and that this technique can be very sensitive to the structural environment of the carbonyl group.
G. Barth, E. Bunnenberg, C. Djerassi, D. Elder and R. Records, Symp. Faraday Soc., 1969, 3, 49 DOI: 10.1039/SF9690300049
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