Sulphoxides are reduced by phosphorus trichloride to the corresponding sulphides in high yields. No chlorination occurs as in the known ‘reduction’ of sulphoxides by phosphorus pentachloride or oxychloride.
I. Granoth, A. Kalir and Z. Pelah, J. Chem. Soc. C, 1969, 2424 DOI: 10.1039/J39690002424
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