1,8-Dehydronaphthalene, generated by oxidation of 1-aminonaphtho[1,8-de]triazine, is a highly reactive species which can be trapped by 1,2-addition to olefins, acetylenes, and by the formation of products apparently arising from radical abstraction. Addition to dimethyl azodicarboxylate gave dimethyl 1,2-dihydrobenz[cd]indazole-1,2-dicarboxylate, an example of the elusive benz[cd]indazole system.
C. W. Rees and R. C. Storr, J. Chem. Soc. C, 1969, 760 DOI: 10.1039/J39690000760
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