A satisfactory demonstration of substantial barriers to internal rotation about the ring-substituent bonds in certain 6β-substituted 5α-cholestanes was not possible, in the main probably because of too high flexibility in the steroid framework.
R. W. Horobin and J. McKenna, J. Chem. Soc. B, 1969, 1018 DOI: 10.1039/J29690001018
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