Issue 0, 1969

Transition metal–carbon bonds. Part XXII. Pyrolysis of some methylplatinum(IV) complexes

Abstract

Some methylplatinum(IV) complexes of the type [PtXyMe4–yL2](X = halogen; y= 0–3; L = PMe2Ph or AsMe2Ph) have been pyrolysed and the gases evolved and the platinum(II) complexes formed have been identified. Acetyl complexes of the type [PtXMe2(COMe)L2] on pyrolysis give acetone and trans-[PtXMeL2] in quantitative yields.

Article information

Article type
Paper

J. Chem. Soc. A, 1969, 2969-2970

Transition metal–carbon bonds. Part XXII. Pyrolysis of some methylplatinum(IV) complexes

J. D. Ruddick and B. L. Shaw, J. Chem. Soc. A, 1969, 2969 DOI: 10.1039/J19690002969

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