Low-pressure hydrogenolysis of the platinum–silicon complex, (Ph2P·CH2·CH2·PPh2)Pt(SiMe3)Cl yields the cis-hydridoplatinum chloride, (Ph2P·CH2·CH2·PPh2)Pt(H)Cl. A re-investigation of the compounds reported to be cis- and trans-(Ph3P)2Pt(H)Cl by using i.r. and 1H n.m.r. spectroscopy shows that they are different crystallo-graphic forms of the trans-isomer.
A. F. Clemmit and F. Glockling, J. Chem. Soc. A, 1969, 2163 DOI: 10.1039/J19690002163
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