Tris(trimethylsilyl)thallium has been prepared in 60% yield by the exchange between trimethylthallium and bis-(trimethylsilyl)mercury. The reactions with hydrogen halides, hydrogen cyanide, and methanol have been studied. With chloroform, bis(trimethylsilyl)thallium chloride is formed.
E. A. V. Ebsworth, A. G. Lee and G. M. Sheldrick, J. Chem. Soc. A, 1969, 1052 DOI: 10.1039/J19690001052
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